Pressure management and cell design in solid-electrolyte batteries, at the example of a sodium-nickel chloride battery

JOURNAL OF POWER SOURCES

卷:465

Article

Heinz, Meike V. F.¹  Graeber, Gustav¹  Landmann, Daniel¹  Battaglia, Corsin¹ 

[1] Empa, Swiss Fed Labs Mat Sci & Technol, CH-8600 Dubendorf, Switzerland

关键词: Solid electrolyte;    Cell design;    Pressure management;    Sodium-nickel chloride battery;    Chemo-mechanical electrode expansion;    Mechanical stress;   

DOI  :  10.1016/j.jpowsour.2020.228268

来源: Elsevier

【 摘 要 】

Solid electrolytes in combination with alkali-metal anodes offer the potential to enhance battery energy density and safety. The inherent challenges associated with cell pressure management have to be accounted for in the cell design but are not sufficiently understood. Here we present a theoretical study linking the effects of thermal and chemo-mechanical expansion of electrode materials to the stresses acting on tubular and planar solid electrolytes, at the example of the sodium-nickel chloride battery chemistry. Based on our analysis, we derive three strategies to reduce these stresses. Namely, we propose (i) to increase the cell closing temperature during production (ii) to reduce the gas pressure in the cell (e.g. by applying a vacuum), and (iii) to rationally balance the volume of the two electrode compartments. Mechanical considerations developed herein form the foundation for the development of next-generation battery cell designs.

【 授权许可】

Free