Consistent diffusivity measurement between Galvanostatic Intermittent Titration Technique and Electrochemical Impedance Spectroscopy

JOURNAL OF POWER SOURCES

卷:473

Article

Deng, Changyu¹  Lu, Wei^1,2 

[1] Univ Michigan, Dept Mech Engn, Ann Arbor, MI 48109 USA

[2] Univ Michigan, Dept Mat Sci & Engn, Ann Arbor, MI 48109 USA

关键词: Lithium ion battery;    Diffusivity;    Galvanostatic intermittent titration technique;    Electrochemical impedance spectroscopy;   

DOI  :  10.1016/j.jpowsour.2020.228613

来源: Elsevier

【 摘 要 】

Galvanostatic Intermittent Titration Technique (GITT) and Electrochemical Impedance Spectroscopy (EIS) are two popular methods to measure the diffusivity of lithium ions in electrode particles. What has puzzled the community for a long time is that these two techniques often give an order of magnitude difference in the results. By analyzing the diffusion profile and approximation error for various particle geometries, we show that these two techniques are consistent only when the current excitation does not impact deep inside the particles, which corresponds to the condition of short pulse time for GITT or high frequency for EIS. GITT does not depend on particle size by its assumption while EIS does. Thus we propose an innovative approach of using EIS to determine diffusivity accurately independent of particle size or geometry. We further demonstrate experimentally that the two techniques yield identical results under the right measurement conditions. This work may provide insight on the scattering of measured diffusivity data in the literature.

【 授权许可】

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