JOURNAL OF POWER SOURCES | 卷:166 |
A computational model of a PEM fuel cell with finite vapor absorption rate | |
Article | |
Vorobev, A. ; Zikanov, O. ; Shamim, T. | |
关键词: PEM fuel cell; modeling; water management; | |
DOI : 10.1016/j.jpowsour.2006.12.071 | |
来源: Elsevier | |
【 摘 要 】
The paper presents a new computational model of non-steady operation of a PEM fuel cell. The model is based on the macroscopic hydrodynamic approach and assumptions of low humidity operation and one-dimensionality of transport processes. Its novelty and advantage in comparison with similar existing models is that it takes into account the finite-time equilibration between vapor and membrane-phase liquid water within the catalyst layers. The phenomenon is described using an additional parameter with the physical meaning of the typical reciprocal time of the equilibration. A computational parametric study is conducted to identify the effect of the finite-time equilibration on steady-state and transient operation of a PEM fuel cell. (c) 2007 Elsevier B.V. All rights reserved.
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