The impact of pH on side reactions for aqueous redox flow batteries based on nitroxyl radical compounds

JOURNAL OF POWER SOURCES

卷:321

Article

Orita, A.^1,2  Verde, M. G.¹  Sakai, M.²  Meng, Y. S.¹ 

[1] Univ Calif San Diego, Dept NanoEngn, 9500 Gilman Dr, La Jolla, CA 92093 USA

[2] Hitachi Chem, Tsukuba Res Lab, 48 Wadai, Tsukuba, Ibaraki 3004247, Japan

关键词: Flow battery;    Aqueous battery;    Radical compound;    TEMPOL;    Zinc anode;   

DOI  :  10.1016/j.jpowsour.2016.04.136

来源: Elsevier

【 摘 要 】

Electrochemical and UV-VIS measurements demonstrate that the pH value of a 4-hydroxy-2,2,6,6-tetramethyl-1-pipperidinyloxyl (TEMPOL) electrolyte significantly impacts its redox reversibility. The diffusion coefficient and kinetic rate constant of TEMPOL in neutral aqueous solution are determined and shown to be comparable to those of vanadium ions used for industrially utilized redox flow batteries (RFBs). RFBs that incorporate a TEMPOL catholyte and Zn-based anolyte have an average voltage of 1.46 V and an energy efficiency of 80.4% during the initial cycle, when subject to a constant current of 10 mA cm(-2). We demonstrate several factors that significantly influence the concentration and capacity retention of TEMPOL upon cycling; namely, pH and atmospheric gases dissolved in electrolyte. We expand upon the known reactions of TEMPOL in aqueous electrolyte and propose several concepts to improve its electrochemical performance in a RFB. Controlling these factors will be the key to enable the successful implementation of this relatively inexpensive and environmentally friendly battery. (C) 2016 Elsevier B.V. All rights reserved.

【 授权许可】

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