Performance of wide temperature range electrolytes for Li-Ion capacitor pouch cells

JOURNAL OF POWER SOURCES

卷:359

Article

Cappetto, A.^2,3,4  Cao, W. J.¹  Luo, J. F.^2,3,4  Hagen, M.^2,3,4  Adams, D.^2,3,4  Shelikeri, A.^2,3,4  Xu, K.⁶  Zheng, J. P.^2,3,4,5 

[1] Gen Capacitor LLC, Tallahassee, FL 32304 USA

[2] Florida A&M Univ, Dept Elect & Comp Engn, Tallahassee, FL 32310 USA

[3] Florida State Univ, Tallahassee, FL 32310 USA

[4] Florida State Univ, Aeroprop Mechatron & Energy AME Ctr, Tallahassee, FL 32310 USA

[5] Florida State Univ, CAPS, Tallahassee, FL 32310 USA

[6] US Army Res Lab, Adelphi, MD USA

关键词: Wide temperature range electrolytes;    Li-ion capacitor;    Pouch cells;    Lithium plating;    Graphite;    Hard carbon;   

DOI  :  10.1016/j.jpowsour.2017.05.071

来源: Elsevier

【 摘 要 】

Four types of wide temperature-range electrolyte formulations based on carbonate and carboxylate esters were evaluated at various temperatures in lithium-ion capacitor (LIC) pouch cells consisting of both hard carbon (HC) and graphite negative electrodes (NEs) with thin lithium foil and an activated carbon (AC) positive electrodes (PEs). The electrolytes containing methyl butyrate (MB) with various additives enabled the LIC to operate at -40 degrees C, where all electrolytes based only on carbonates fail. MB-containing electrolyte with lithium Difluoro(oxalato) borate (LiDFOB) as additive showed the best cycling performance over 5000 cycles. Lithium plating also occurred on graphite NEs when charged at low temperatures starting at -20 degrees C, which resulted in the non-linear curves. When charged at 30 degrees C and discharged at -40 degrees C, graphite NE based LIC displayed regular linear charge-discharge curves without lithium plating. In comparison, HC NE based LICs showed better capacity retention at -40 degrees C and no signs of lithium plating. It could be concluded that low temperature performance of LIC was influenced by both electrolyte formulations and negative electrode material. (C) 2017 Elsevier B.V. All rights reserved.

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