Accelerated creep in solid oxide fuel cell anode supports during reduction

JOURNAL OF POWER SOURCES

卷:323

Article

Frandsen, H. L.¹  Makowska, M.^1,2  Greco, F.¹  Chatzichristodoulou, C.¹  Ni, D. W.¹  Curran, D. J.¹  Strobl, M.²  Kuhn, L. T.¹  Hendriksen, P. V.¹ 

[1] Tech Univ Denmark, Dept Energy Convers & Storage, Roskilde, Denmark

[2] European Spallat Source AB, Div Sci, Lund, Sweden

关键词: Creep;    Reduction;    SOFC;    SOEC;    Ni-YSZ;    Chemo-mechanical coupling;   

DOI  :  10.1016/j.jpowsour.2016.04.097

来源: Elsevier

【 摘 要 】

To evaluate the reliability of solid oxide fuel cell (SOFC) stacks during operation, the stress field in the stack must be known. During operation the stress field will depend on time as creep processes relax stresses. The creep of reduced Ni-YSZ anode support at operating conditions has been studied previously. In this work a newly discovered creep phenomenon taking place during the reduction is reported. This relaxes stresses at a much higher rate (similar to x10(4)) than creep during operation. The phenomenon was studied both in three-point bending and uniaxial tension. Differences between the two measurements could be explained by newly observed stress promoted reduction. Finally, samples exposed to a small tensile stress (similar to 0.004 MPa) were observed to expand during reduction, which is in contradiction to previous literature. These observations suggest that release of internal residual stresses between the NiO and the YSZ phases occurs during reduction. The accelerated creep should practically eliminate any residual stress in the anode support in an SOFC stack, as has previously been indirectly observed. This phenomenon has to be taken into account both in the production of stacks and in the simulation of the stress field in a stack based on anode supported SOFCs. (C) 2016 Elsevier B.V. All rights reserved.

【 授权许可】

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