Impact of solute concentration on the electrocatalytic conversion of dissolved gases in buffered solutions

JOURNAL OF POWER SOURCES

卷:287

Article

Shinagawa, Tatsuya¹  Takanabe, Kazuhiro¹ 

[1] KAUST, Catalysis Ctr KCC, Div Phys Sci & Engn, Thuwal 239556900, Saudi Arabia

关键词: Fuel cells;    Oxygen reduction reaction;    Hydrogen oxidation reaction;    Conductivity;    Solution resistance;   

DOI  :  10.1016/j.jpowsour.2015.04.091

来源: Elsevier

【 摘 要 】

To maintain local pH levels near the electrode during electrochemical reactions, the use of buffer solutions is effective. Nevertheless, the critical effects of the buffer concentration on electrocatalytic performances have not been discussed in detail. In this study, two fundamental electrochemical reactions, oxygen reduction reaction (ORR) and hydrogen oxidation reaction (HOR), on a platinum rotating disk electrode are chosen as model gas-related aqueous electrochemical reactions at various phosphate concentrations. Our detailed investigations revealed that the kinetic and limiting diffusion current densities for both the ORR and HOR logarithmically decrease with increasing solute concentration (log vertical bar j(ORR)vertical bar = -0.39c + 0.92, log vertical bar j(HOR)vertical bar = -0.35c + 0.73). To clarify the physical aspects of this phenomenon, the electrolyte characteristics are addressed: with increasing phosphate concentration, the gas solubility decrease, the kinematic viscosity of the solution increase and the diffusion coefficient of the dissolved gases decrease. The simulated limiting diffusion currents using the aforementioned parameters match the measured ones very well (log vertical bar j(ORR)vertical bar = -0.43c + 0.99, job vertical bar j(HOR)vertical bar = -0.40c + 0.54), accurately describing the consequences of the electrolyte concentration. These alterations of the electrolyte properties associated with the solute concentration are universally applicable to other aqueous gas-related electrochemical reactions because the currents are purely determined by mass transfer of the dissolved gases. (C) 2015 The Authors. Published by Elsevier B.V.

【 授权许可】

Free