Revealing the chemical environment of Cr, Fe, and Ni in high temperature-ultrafine precipitate strengthened steel subjected to low fluence neutron irradiation

JOURNAL OF NUCLEAR MATERIALS

卷:554

Article

Nori, Sri Tapaswi¹  Park, Gyuchul¹  Williams, Walter^1,2  Lee, Zhengrong³  Warren, Mark³  Terry, Jeff³  Park, Jun-Sang⁴  Kenesei, Peter⁴  Almer, Jonathan⁴  Okuniewski, Maria A.¹ 

[1] Purdue Univ, Sch Mat Engn, W Lafayette, IN 47907 USA

[2] Idaho Natl Lab, Idaho Falls, ID USA

[3] IIT, Dept Phys, Chicago, IL 60616 USA

[4] Argonne Natl Lab, Adv Photon Source, Lemont, IL USA

关键词: HT-UPS steel;    Neutron irradiation;    X-ray absorption near edge structure;    High-energy X-ray diffraction;    Cr23C6;   

DOI  :  10.1016/j.jnucmat.2021.153056

来源: Elsevier

【 摘 要 】

High temperature-ultrafine precipitate strengthened (HT-UPS) steel has potential applications in advanced nuclear reactors as a structural material. However, little is currently known about its response to neutron irradiation. This research provides insight into the neutron irradiation-induced physicochemical changes of the major constituents in HT-UPS steels, including Fe, Cr, and Ni, using synchrotron X-ray absorption near edge structure (XANES) and diffraction. This study is the first known investigation using XANES to characterize HT-UPS steel to analyze the evolution of the atomic level chemistry. It was found that following neutron exposure, radiation-induced nucleation, growth, and/or ballistic dispersion of Cr23C6 precipitates occurred at very low neutron irradiation fluences, from 0.003 displacements per atom (dpa) up to 0.3 dpa, at 600 degrees C, which were at least an order of magnitude lower than previous studies. Calculations of the angular momentum projected partial density of states and the XANES spectra confirmed the experimental findings of the Cr23C6 precipitate evolution. In contrast, the local atomic structure around Fe and Ni atoms demonstrated irradiation resistance. (C) 2021 Elsevier B.V. All rights reserved.

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