Evolution of Microstructure and Surface Characteristics of FeCrAl alloys when Subjected to Flow Boiling Testing

JOURNAL OF NUCLEAR MATERIALS

卷:557

Article

V. Umretiya, Rajnikant¹  Lee, Donghwi²  Elward, Barret²  Anderson, Mark²  Rebak, Raul B.³  V. Rojas, Jessika¹ 

[1] Virginia Commonwealth Univ, Dept Mech & Nucl Engn, Richmond, VA 23284 USA

[2] Univ Wisconsin, Dept Mech Engn, Madison, WI USA

[3] GE Res, Schenectady, NY 12309 USA

关键词: Accident tolerant fuel;    ATF;    FeCrAl alloys;    APMT;    C26M;    Critical heat flux (CHF);    surface chemistry;    wettability;   

DOI  :  10.1016/j.jnucmat.2021.153269

来源: Elsevier

【 摘 要 】

FeCrAl alloys are candidate materials for manufacturing accident-tolerant fuel (ATF) cladding intended for light water reactors to increase fuel reliability and safety during design-basis and beyond-design-basis accident scenarios. The evolution of the materials' surface characteristics, microstructure, and mechanical properties when exposed to the Critical Heat Flux (CHF) in flow boiling testing is crucial for safety analysis while providing insights into their thermal-hydraulic performance in nuclear reactors. After CHF, the surface chemistry of two FeCrAl alloys, APMT and C26M, was studied to understand their evolution at the early stage of high-temperature excursions in short time periods. The results indicated a thin layer composed of oxides and hydroxides of Al, Cr, and Fe with varying proportions at different depths in the layer, as indicated by X-ray photoelectron spectroscopy (XPS) and depth profiling. The cross-sections prepared by focused ion beam (FIB) revealed the growth of an oxide layer, in the range of 90-180 nm thick, on the alloys' surfaces. The evolution of the materials' surface chemistry also led to a noticeable post CHF excursion increase in their wettability, with a slight increase in roughness. The investigation of the materials' mechanical properties indicated a modest increase in hardness by 10-15% as well as an increase in their yield strength, as evidenced by the microindentation and ring compression tests conducted before and after CHF testing. Scanning electron Microscopy (SEM) and X-ray diffraction (XRD) were used to investigate microstructural features of the materials and their changes after CHF treatment. (c) 2021 Elsevier B.V. All rights reserved.

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