High temperature Cr-Zr interaction of two types of Cr-coated Zr alloys in inert gas environment

JOURNAL OF NUCLEAR MATERIALS

卷:547

Article

Yang, Jianqiao^1,2  Stegmaier, Ulrike¹  Tang, Chongchong¹  Steinbrueck, Martin¹  Grosse, Mirco¹  Wang, Shuzhong²  Seifert, Hans Jurgen¹ 

[1] Karlsruhe Inst Technol KIT, Inst Appl Mat IAM, D-76021 Karlsruhe, Germany

[2] Xi An Jiao Tong Univ, Sch Energy & Power Engn, Key Lab Thermofluid Sci & Engn MOE, 28 Xianning West Rd, Xian 710049, Peoples R China

关键词: Accident tolerant fuel cladding;    Magnetron sputtering;    Cold spraying;    Chromium coating;    Zirconium alloy;    Kinetic parameters;   

DOI  :  10.1016/j.jnucmat.2021.152806

来源: Elsevier

【 摘 要 】

The Cr-Zr interaction of two types of Cr coated Zr alloy accident tolerant fuel (ATF) claddings, deposited by cold spraying and magnetron sputtering, was studied in argon in the temperature range from 1100 to 1300 degrees C. A tube furnace with a sample lock system was used for fast exchanging samples at test temperature. Inter-diffusion between the coating and the substrate results in the formation of an intermetallic ZrCr2 layer and a solid solution layer beneath. Some pores were formed on the interlayer by a Kirkendall-type mechanism. The interlayer growth rate of cold sprayed samples was always slightly higher than that of magnetron sputtered samples in the same condition. Moreover, the temperature-dependent consumption coefficient of the Cr coating was calculated and fitted to an Arrhenius function. The dissolution and precipitation behavior of Cr in the Zr substrate and the diffusion behavior of Zr in Cr coating were also studied. (C) 2021 Elsevier B.V. All rights reserved.

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