Lithiation of the Fe2P-based magnetocaloric materials: A first-principles study

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS

卷:537

Article

Batashev, I.¹  de Wijs, G. A.²  van Dijk, N. H.¹  Bruck, E.¹ 

[1] Delft Univ Technol, Fundamental Aspects Mat & Energy FAME, NL-2629 JB Delft, Netherlands

[2] Radboud Univ Nijmegen, Inst Mol & Mat, Heyendaalseweg 135, NL-6525 AJ Nijmegen, Netherlands

关键词: Magnetocaloric effect;    DFT;    First-principles calculations;    Magnetic refrigeration;    Curie temperature;    Fe2P;   

DOI  :  10.1016/j.jmmm.2021.168179

来源: Elsevier

【 摘 要 】

The physical properties of the extensively studied Fe2P material family, well-known for its promising magnetocaloric qualities are greatly influenced by the unit-cell parameters of this hexagonal system. This sensitivity of the various magnetocaloric properties to structural parameters is particularly important for developing a material suitable for room-temperature magnetic refrigeration. A change in the unit cell, due to added elements can induce pronounced changes in the Curie temperature and the nature of the magnetic phase transition. Li belongs to a yet unexplored group of possible dopant elements - alkali metals, and exhibits an unusual behavior upon introduction to Fe2P. We observe a preference to replace iron atoms, as opposed to the common tendency of nonmagnetic dopants to replace phosphorus, leading to a strong influence on the magnetic structure. The addition of Li introduces a deformation of the unit cell with a small change in volume and a decrease in c/a ratio, while the same crystallographic phase is maintained over a relatively wide concentration range. We show that lithium has an exceptionally strong effect on the Curie temperature of Fe2P reaching 800 K at 20% Li compared to 240 K for the undoped material.

【 授权许可】

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