Tunable one-dimensional assembly of magnetic nanoparticles using oscillating magnetic fields at low frequencies for polymer nanocomposite fabrication

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS

卷:468

Article

Spencer, Mychal P.¹  Gao, David¹  Yamamoto, Namiko¹ 

[1] Penn State Univ, Dept Aerosp Engn, University Pk, PA 16802 USA

关键词: Magnetic assembly;    Oscillating field;    Iron oxide;    Nanoparticles;    Nanocomposites;    Polymer-matrix composites;   

DOI  :  10.1016/j.jmmm.2018.08.006

来源: Elsevier

【 摘 要 】

Tunable, one-dimensional (1D) nanofiller assembly using oscillating magnetic fields in the low frequency range ( < 5 Hz) is studied as a scalable and energy-efficient method to structure nanofillers within viscous matrices to deliver anisotropic, multi-functional polymer nanocomposites (PNCs). In this work 1D assembly tailoring was first experimentally studied and demonstrated using the model system of superparamagnetic iron oxide nanoparticles (SPIONs, 15 nm, 0.02-0.08 vol%) in DI water using varying magnetic fields (0-5 Hz frequency, 10-100 G magnetic flux density, and square and sinusoidal waveforms). In addition to lateral assembly of nanofillers, when the field oscillation is turned on, transverse assembly can be introduced as the magnetic moments of the particles respond to the changing fields by Brownian rotation. The degree of transverse assembly, in balance with lateral assembly and the resulting nanofiller patterns, was observed to be determined by the magnetic field parameters, magnetic responsiveness of the nanofillers, and the matrix viscosity. Based on this assembly study, PNCs consisting of ferrimagnetic iron oxide nanofillers in a thermoset polymer, with two different linear nanoparticle patterning, were successfully fabricated using small magnetic fields ( < 100 G) even in a viscous matrix (70 cP) with a short assembly time of 30 min. This work can contribute to scalable manufacturing and thus bulk application of multi-functional PNCs enabled by more precise nanofiller and interface structuring.

【 授权许可】

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