EXAFS as a probe of actinide oxide formation in the tender X-ray regime

SURFACE SCIENCE

卷:698

Article

Tobin, J. G.¹  Nowak, S. H.²  Yu, S-W³  Alonso-Mori, R.²  Kroll, T.²  Nordlund, D.²  Weng, T-C²  Sokaras, D.² 

[1] Univ Wisconsin, Oshkosh, WI 54901 USA

[2] SLAC Natl Accelerator Lab, Menlo Pk, CA 94025 USA

[3] Lawrence Livermore Natl Lab, Livermore, CA 94550 USA

关键词: Uranium;    X-ray Emission Spectroscopy;    Actinides;    5f electrons;   

DOI  :  10.1016/j.susc.2020.121607

来源: Elsevier

【 摘 要 】

Recent developments in Resonant Inelastic X-Ray Scattering Experiments have vastly improved the resolution in X-ray Spectroscopies such as X-ray Absorption. However, the use of Tender X-rays (similar to 3 keV) and the reactivity of actinides such as uranium have given rise to new questions about bulk and surface sensitivity, what constitutes a surface and how to characterize the formation of an oxide. It will be shown that the in situ electron scattering features that are part of the RIXS spectrum can be used to quantify the uranium oxide formation and determine cleanliness, independently of the near edge features that provide information about the unoccupied electronic density of states.

【 授权许可】

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