Mechanical alloying produces grain boundary segregation in Fe-Mg powders

SCRIPTA MATERIALIA

卷:180

Article

Amram, Dor¹  Schuh, Christopher A.¹ 

[1] MIT, Dept Mat Sci & Engn, 77 Massachusetts Ave,Bldg 8-139, Cambridge, MA 02139 USA

关键词: Nanocrystalline metal;    Grain boundary segregation;    Mechanical alloying;    Ball mill;    Iron alloys;   

DOI  :  10.1016/j.scriptamat.2020.01.021

来源: Elsevier

【 摘 要 】

Although mechanical alloying can force immiscible elements into homogeneous solid solution due to its chemically randomizing nature, as microstructure design of powder-processed alloys advances, other alloy configurations are also sought. Here we study ball milling of Fe-Mg alloys and obtain a heterogeneous nanostructure, with grain boundaries decorated by solute even after reaching complete supersaturation and a steady-state grain size. Such nanocrystalline powders having grain boundary segregation in the as-milled state are particularly useful for thermal stability against grain growth. The high diffusivity of Mg is thought to shift the competition between ballistic mixing and equilibration, permitting such a structure to form. (C) 2020 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

【 授权许可】

Free