Effect of Cu addition as a promoter on Re/SiO2 catalysts in the hydrodeoxygenation of 2-methoxyphenol as a model bio oil compound

FUEL

卷:186

Article

Martinez, N.¹  Garcia, R.¹  Fierro, J. L. G.²  Wheeler, C.^3,4  Austin, R. N.^3,4  Gallagher, J. R.⁵  Miller, J. T.⁶  Krause, T. R.⁵  Escalona, N.^7,8  Sepulveda, C.¹ 

[1] Univ Concepcion, Fac Ciencias Quim, Casilla 160C, Concepcion, Chile

[2] CSIC, Inst Catalisis & Petroquim, Madrid 28049, Spain

[3] Univ Maine, Dept Chem & Biol Engn, Orono, ME 04469 USA

[4] Univ Maine, Forest Bioprod Res Inst, Orono, ME 04469 USA

[5] Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA

[6] Purdue Univ, Sch Chem Engn, W Lafayette, IN 47907 USA

[7] Pontificia Univ Catolica Chile, Dept Ingn Quim & Bioproc, Escuela Ingn, Ave Vicuna Mackenna 4860, Santiago, Chile

[8] Pontificia Univ Catolica Chile, Dept Quim Fis, Fac Quim, Santiago, Chile

关键词: Cu promoter;    Re metal;    Hydrodeoxygenation;    Active sites;    Hydrogen spillover;   

DOI  :  10.1016/j.fuel.2016.08.065

来源: Elsevier

【 摘 要 】

The promoting effect of Cu on Re/SiO2 catalysts was studied for guaiacol hydrodeoxygenation. Cu(x)Re/SiO2 catalysts containing from 0 to 1.91 wt% Cu and 13 wt% of Re were prepared by successive wet impregnation and characterized using X-ray diffraction (XRD), nitrogen sorption, CO chemisorption, X-ray photoelectron spectroscopy (XPS), X-ray absorption spectroscopy (XAS) and surface acidity techniques. Batch reactions were carried out at 300 degrees C and 5 MPa of H-2. The Cu(x)Re/SiO2 catalysts displayed higher activities than the Re/SiO2 catalyst with a maximum activity at 1.58 wt% Cu. At loadings above 1.5 wt%, aggregate formation and a loss of metallic Re active sites lead to a decreased activity. The increase of the activity was attributed not only to Cu increasing the Re reducibility, but also to Cu somehow increasing the metallic Re active sites favoring guaiacol conversion. All catalysts displayed the same product distribution, confirming that the Cu in the Cu(x)Re/SiO2 not change the nature of the active site in the metallic Re nanoparticles. (C) 2016 Elsevier Ltd. All rights reserved.

【 授权许可】

Free