Estimation and modeling of coal pore accessibility using small angle neutron scattering

FUEL

卷:161

Article

Zhang, Rui^1,2  Liu, Shimin^1,2  Bahadur, Jitendra³  Elsworth, Derek^1,2  Melnichenko, Yuri³  He, Lilin³  Wang, Yi^1,2 

[1] Penn State Univ, Ctr G3, Dept Energy & Mineral Engn, University Pk, PA 16802 USA

[2] Penn State Univ, Energy Inst, University Pk, PA 16802 USA

[3] Oak Ridge Natl Lab, Biol & Soft Matter Div, Neutron Sci Directorate, Oak Ridge, TN 37831 USA

关键词: Pore accessibility;    SANS;    Coal pore characterization;    Accessibility modeling;   

DOI  :  10.1016/j.fuel.2015.08.067

来源: Elsevier

【 摘 要 】

Gas diffusion in coal is controlled by nano-structure of the pores. The interconnectivity of pores not only determines the dynamics of gas transport in the coal matrix but also influences the mechanical strength. In this study, small angle neutron scattering (SANS) was employed to quantify pore accessibility for two coal samples, one of sub-bituminous rank and the other of anthracite rank. A theoretical pore accessibility model was proposed based on scattering intensities under both vacuum and zero average contrast (ZAC) conditions. The results show that scattering intensity decreases with increasing gas pressure using deuterated methane (CD4) at low Q values for both coals. Pores smaller than 40 nm in radius are less accessible for anthracite than sub-bituminous coal. On the contrary, when the pore radius is larger than 40 nm, the pore accessibility of anthracite becomes larger than that of sub-bituminous coal. Only 20% of pores are accessible to CD4 for anthracite and 37% for sub-bituminous coal, where the pore radius is 16 nm. For these two coals, pore accessibility and pore radius follows a power-law relationship. (C) 2015 Elsevier Ltd. All rights reserved.

【 授权许可】

Free