Effects of iron-based fuel borne catalyst addition on microstructure, element composition and oxidation activity of diesel exhaust particles

FUEL

卷:270

Article

Liu, Junheng¹  Wang, Lejian¹  Sun, Ping¹  Wang, Pan¹  Li, Yuqiang²  Ma, Hongjie³  Wu, Pengcheng¹  Liu, Zengguang¹ 

[1] Jiangsu Univ, Sch Automot & Traff Engn, Zhenjiang 212013, Jiangsu, Peoples R China

[2] Cent South Univ, Sch Energy Sci & Engn, Changsha 410083, Peoples R China

[3] Univ Portsmouth, Inst Ind Res, Portsmouth PO1 2EG, Hants, England

关键词: Common-rail engine;    Iron-based fuel borne catalyst;    Soot oxidation;    Particle size distribution;    Element composition;    Particulate matter;   

DOI  :  10.1016/j.fuel.2020.117597

来源: Elsevier

【 摘 要 】

Metal-based fuel borne catalysts (FBC) have been extensively studied as an effective technology to reduce diesel particles and assist diesel particulate filter (DPF) regeneration. In this study, FBC fuels were prepared with Fe element mass fractions of 0, 100, 200, 300 and 400 mg/kg (marked as Diesel, Fe100, Fe200, Fe300 and Fe400). The effects of FBC additions on fuel economy and emission characteristics were carried out on a common-rail engine. Also, particle size distribution, microstructure, surface functional groups, element content and oxidation properties of exhaust particles were systematically analyzed. Results showed that the brake thermal efficiency was improved with the addition of FBC in diesel fuel, especially at low load, and the NOx and smoke emissions showed a decreasing trend. Compared with Diesel particles, the total mass concentration and the mean particle diameter of Fe300 particles decreased, the overall particle size distribution moved from coarse mode to accumulation mode, however, the total number concentration increased. Fe300 particles had larger layer spacing and microcrystalline curvature, smaller microcrystalline size and lower graphitization. In addition, the relative contents of OH and aliphatic C-H in Fe300 particles were higher than those in Diesel particles. The relative content of C atoms in Fe300 particles decreased, while the relative content of O atoms increased. Temperatureprogrammed-oxidation experiments indicated that semi-volatile organic components appeared in Fe300 particles, the peak temperature of weight loss rate decreased by 131 degrees C as compared with Diesel particles, the activation energy was also significantly lower, and therefore the particle oxidation activity was improved.

【 授权许可】

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