Physicochemical property changes during oxidation process for diesel PM sampled at different tailpipe positions

FUEL

卷:219

Article

Gao, Jianbing^1,2  Tian, Guohong¹  Ma, Chaochen²  Chen, Junyan³  Huang, Liyong² 

[1] Univ Surrey, Dept Mech Engn Sci, Guildford GU2 7XH, Surrey, England

[2] Beijing Inst Technol, Sch Mech Engn, Beijing 100081, Peoples R China

[3] Shanxi Univ, Coll Environm Sci & Resource, Taiyuan 030006, Shanxi, Peoples R China

关键词: Diesel PM;    Sampling temperature;    Partial oxidation;    Physicochemical properties;   

DOI  :  10.1016/j.fuel.2018.01.074

来源: Elsevier

【 摘 要 】

Diesel particulate matter (PM) samples were collected at different tailpipe positions where sampling temperature differed greatly. All the samples were pre-heated in air at high temperature until 40% mass was burnt out. Physicochemical properties of diesel PM both before and after partial oxidation were analyzed, and to further figure out the reasons of oxidation activity changes in the oxidation process. The results showed that ignition temperature of PM whose sampling temperature was higher than 208 degrees C differed greatly from PM sampled below that temperature. After partial oxidation, sample 3 presented the hugest oxidation activity decreasing with burn out temperature increasing by 14.7 degrees C. Primary particle size distribution shifted to smaller diameter direction after partial oxidation, and particle stacking degree decreased evidently. Nanostructures of diesel PM transferred from onion like structures with randomly arranged crystallite to core-shell like structures with void inner cores. Oxygen-containing functional groups (carbonyl and hydroxy) decreased evidently after PM partial oxidation that was obtained from Fourier transform infrared spectroscopy (FTIR) spectra, it was consistent with the results of Raman parameter I-D3/I-G.

【 授权许可】

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