Mass spectra of cyclic ethers formed in the low-temperature oxidation of a series of n-alkanes

FUEL

卷:90

Article

Herbinet, Olivier¹  Carre, Vincent² 

[1] Nancy Univ, Lab React & Genie Procedes, Ecole Natl Super Ind Chim, CNRS,UPR 3349, F-54000 Nancy, France

[2] Univ Paul Verlaine Metz, Inst Jean Barriol Federat Rech 2843, Lab Spectrometrie Masse & Chim Laser, F-57078 Metz 03, Technopole, France

关键词: Cyclic ether;    Engine exhaust gases;    Combusion;    n-Alkanes;    Mass spectrum;   

DOI  :  10.1016/j.fuel.2010.09.047

来源: Elsevier

【 摘 要 】

Cyclic ethers are important intermediate species formed during the low-temperature oxidation of hydrocarbons. Along with ketones and aldehydes, they could consequently represent a significant part of the heavy oxygenated pollutants observed in the exhaust gas of engines. Apart a few of them such as ethylene oxide and tetrahydrofuran, cyclic ethers have not been much studied and very few of them are available for calibration and identification. Electron impact mass spectra are available for very few of them, making their detection in the exhaust emissions of combustion processes very difficult. The main goal of this study was to complete the existing set of mass spectra for this class of molecules. Thus cyclic ethers have been analyzed in the exhaust gases of a jet-stirred reactor in which the low-temperature oxidation of a series of n-alkanes was taking place. Analyzes were performed by gas chromatography coupled to mass spectrometry and to MS/MS. The second goal of this study was to derive some rules for the fragmentation of cyclic ethers in electron impact mass spectrometry and allow the identification of these species when no mass spectrum is available. (C) 2010 Elsevier Ltd. All rights reserved.

【 授权许可】

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