Preparation and evaluation of Co/Al2O3 catalysts in the production of hydrogen from thermo-catalytic decomposition of methane:: Influence of operating conditions on catalyst performance

FUEL

卷:87

Article

Nuernberg, Giselle B.¹  Fajardo, Humberto V.¹  Mezalira, Daniela Z.¹  Casarin, Tamara J.¹  Probst, Luiz F. D.¹  Carreno, Neftalfli L. V.² 

[1] Univ Fed Santa Catarina, Dept Quim, BR-88040900 Florianopolis, SC, Brazil

[2] Univ Fed Pelotas, Inst Quim & Geosci, Dept Quim Analit & Inorgan, BR-96010900 Pelotas, RS, Brazil

关键词: hydrogen;    methane decomposition;    catalysis;   

DOI  :  10.1016/j.fuel.2007.08.005

来源: Elsevier

【 摘 要 】

This paper presents the synthesis of Co-doped Al2O3 catalysts, developed by our group, with porous structures and high surface areas. The catalytic activity of the materials obtained was evaluated in the catalytic decomposition of methane, which is an attractive method for CO/CO2-free production of hydrogen, particularly for fuel cell applications. The catalysts were shown to be active and stable in relation to the catalytic decomposition of methane reaction. It was observed that the catalytic performance is dependent on the catalyst characteristics and on the operational conditions employed. The conversion of methane increased with metal loading, reaction temperature and N-2:CH4 molar ratio. (C) 2007 Elsevier Ltd. All rights reserved.

【 授权许可】

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