Assessment of sulfur trioxide formation due to enhanced interaction of nitrogen oxides and sulfur oxides in pressurized oxy-combustion

FUEL

卷:290

Article

Wang, Xuebin¹  Yablonsky, Gregory S.³  Rahman, Zia Ur¹  Yang, Zhiwei²  Du, Pan²  Tan, Houzhang¹  Axelbaum, Richard L.² 

[1] Xi An Jiao Tong Univ, MOE Key Lab Thermofluid Sci & Engn, Xian 710049, Shaanxi, Peoples R China

[2] Washington Univ St Louis, Dept Energy Environm & Chem Engn, Consortium Clean Coal Utilizat, St Louis, MO 63130 USA

[3] St Louis Univ, Pk Coll Engn Aviat & Technol, St Louis, MO 63103 USA

关键词: Pressurized oxy-combustion;    SO3;    NO2;    Kinetic mechanism;    Interaction;   

DOI  :  10.1016/j.fuel.2020.119964

来源: Elsevier

【 摘 要 】

Pressurized oxy-combustion is emerging to be one of the best technologies for significantly decreasing the energy penalty for CO2 capture in coal-fired power plants. However, the higher pressure boosts the formation of acid gases, including SO3 and NO2, which could increase the risk of corrosion. The synergistic promotion of SO3 and NO2 formation in pressurized oxy-combustion is kinetically evaluated under representative conditions (1 similar to 30 atm, 600 similar to 1200 degrees C, NO/SO2 = 0.1 similar to 5). We begin with a comprehensive mechanism (72 species and 428 reactions), covering nitrogen and sulfur chemistry, relying on GRI-Mech 3.0. This analysis shows that the interaction of SOX and NOX enhances the conversion rates of SO2 -> SO3, and this effect is more apparent at elevated pressures and lower temperatures. Mechanism analyses indicate that at elevated pressures, the formation pathways of SO3 through HOSO2 + O-2 = SO3 + HO2, and NO2 through HO2 + NO = NO2 + OH, are promoted due to the strong interaction between SOX and NOX. The intermediate between these two reactions is SO2 + OH + M = HOSO2 + M, resulting in a strong cycle, that can be expressed by the global reaction NO + SO2 + O-2 = NO2 + SO3. Finally, a nine-step reduced chemistry is developed and validated to accurately predict the formation of SO3 in the post-flame region at elevated pressures.

【 授权许可】

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