Microporous carbon monolith synthesis and production for methane storage

FUEL

卷:200

Article

Rash, T. A.¹  Gillespie, A.¹  Holbrook, B. P.²  Hiltzik, L. H.²  Romanos, J.³  Soo, Y. C.¹  Sweany, S.¹  Pfeifer, P.¹ 

[1] Univ Missouri, Dept Phys & Astron, Columbia, MO 65211 USA

[2] Ingevity, 5255 Virginia Ave, N Charleston, SC 29406 USA

[3] Lebanese Amer Univ, Dept Nat Sci, Byblos, Lebanon

关键词: Storage;    Adsorbents;    Carbon;    Methane;    Natural gas;   

DOI  :  10.1016/j.fuel.2017.03.037

来源: Elsevier

【 摘 要 】

The synthesis, characterization, and performance of a new low pressure, monolithic, activated carbon adsorbent developed for methane storage is discussed and compared to other adsorbents. The effect of particle packing density on the storage capacity of tanks filled with commercially available and developmental adsorbents is quantified. 20 kg of the developed monolithic material is tested using a custom built, 40 L, space conformable tank test assembly. The performance is found to be superior to metal organic frameworks and other activated carbons reported in literature based on high tank volumetric and gravimetric storage capacities. The developed material has a pore structure and external dimensions that allow for rapid adsorption/desorption with gas being able to reach the center of the 40 L tank within similar to 3 s. The developed material delivers 151 V/V of methane between 35 bar and 1 bar in the 40 L tank. A continuous discharge flow rate of 2 g/s at 5 bar for a 10 gge system was demonstrated. (C) 2017 Elsevier Ltd. All rights reserved.

【 授权许可】

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