Increasing the chlorine active sites in the micropores of biochar for improved mercury adsorption

FUEL

卷:229

Article

Wang, Tao¹  Wu, Jiawen¹  Zhang, Yongsheng¹  Liu, Jun¹  Sui, Zifeng¹  Zhang, Huicong¹  Chen, Wei-Yin²  Norris, Pauline³  Pan, Wei-Ping^1,3 

[1] North China Elect Power Univ, Minist Educ, Key Lab Condit Monitoring & Control Power Plant E, Beijing 102206, Peoples R China

[2] Univ Mississippi, Dept Chem Engn, 134 Anderson Hall, University, MS 38677 USA

[3] Western Kentucky Univ, Inst Combust Sci & Environm Technol, Bowling Green, KY 42101 USA

关键词: Chlorine modification;    Biochar;    Mechanism;    Elemental mercury;    Flue gas;   

DOI  :  10.1016/j.fuel.2018.05.028

来源: Elsevier

【 摘 要 】

A series of biochars were prepared from rice(RI), tobacco(TO), corn(CO), wheat(WH), millet(MI), and black bean straw(BB). These biochars were used to study the mechanism of elemental mercury(Hg-0) adsorption by hydrochloric acid modified biochars. The biochars were modified by 1M hydrochloric acid (HCl) and then used in a fixed-bed Hg-0 adsorption experiment. As would be expected, the results indicated that HCl modification increased the Hg-0 adsorption performance of the six biochars. After modification, the Hg-0 adsorption efficiency of tobacco biochar increased from 8.2% to 100.0%, and the average Hg-0 adsorption capacity of the biochars increased by 61 times. The acid modification dissolved the metal compounds in the biochar, reducing the metal content and increasing the average surface area of the biochar. The average surface area of the raw biochars increased from 29.9 to 110.1 m(2)/g after HCl modification. The extra surface area was mostly created in the micropores, leading to a significant increase in the amount of micropores. These micropores effectively adsorbed the Cl atoms, which acted as active sites for Hg-0. In the adsorption process, Hg-0 diffused into the interior of modified biochars via mesopores, and finally the adsorbed Cl in the micropores reacted with Hg-0 to form HgCl2.

【 授权许可】

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