Steam reforming of phenol as biomass tar model compound over Ni/Al2O3 catalyst

FUEL

卷:184

Article

Artetxe, Maite²  Nahil, Mohamad A.¹  Olazar, Martin²  Williams, Paul T.¹ 

[1] Univ Leeds, Energy Res Inst, Leeds LS2 9JT, W Yorkshire, England

[2] Univ Basque Country, Dept Chem Engn, POB 644, E-48080 Bilbao, Spain

关键词: Ni/Al2O3 catalyst;    Biomass gasification;    Tar model compound;    Phenol;    Steam reforming;   

DOI  :  10.1016/j.fuel.2016.07.036

来源: Elsevier

【 摘 要 】

Catalytic steam reforming of phenol over Ni/Al2O3 catalyst with 10 wt% of Ni loading was carried out in a fixed bed reactor. The effect of temperature (650-800 degrees C), reaction time (20-80 min) and catalyst amount (0-2 g corresponding to 0-4.5 g(cat) h g(phenol)(1)) on carbon conversion, H-2 potential and catalyst deactivation was studied. High efficiency of Ni/Al2O3 catalyst in steam reforming of phenol is observed at 750 degrees C for a reaction time of 60 min when 1.5 g of catalyst (3.4 g(cat) h g(phenol)(1)) is used, with carbon conversion and H2 potential being 81 and 59%, respectively. An increase in temperature enhances phenol reforming reaction as well as coke gasification, minimizing its deposition over the catalyst. However, at high temperatures (800 degrees C) an increase in Ni crystal size is observed indicating catalyst irreversible deactivation by sintering. As catalyst time on stream is increased the coke amount deposited over the catalyst increases, but no differences in Ni crystal size are observed. An increase in catalyst amount from 0 to 1.5 g increases H-2 potential, but no further improvement is observed above 1.5 g. It is not observed significant catalyst deactivation by coke deposition, with the coke amount deposited over the catalyst being lower than 5% in all the runs. (C) 2016 Elsevier Ltd. All rights reserved.

【 授权许可】

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