Controlling the assembly of hydrophobized gold nanoparticles at the air-water interface by varying the interfacial tension

THIN SOLID FILMS

卷:519

Article; Proceedings Paper

Gupta, Shweta¹  Singh, Nahar¹  Sastry, Murali²  Kakkar, Rita³  Pasricha, Renu¹ 

[1] Natl Phys Lab, Mat Characterizat Div, New Delhi 110012, India

[2] Tata Chem Innovat Ctr, Pune 45, Maharashtra, India

[3] Univ Delhi, Dept Chem, Delhi 110007, India

关键词: Gold nanoparticles;    Langmuir-Blodgett technique;    Lipid monolayer;   

DOI  :  10.1016/j.tsf.2010.08.046

来源: Elsevier

【 摘 要 】

Controlled assembly is the key to harness the nanoscale properties of nanoparticles in most technological applications and it has been an important challenge as it leads to the manipulation of interparticle properties. The present work depicts the control of the assembly of nanoparticles in the monolayers by evaporation kinetics and particle interactions at the air-liquid interface. In the presence of attractive particle-particle and particle-monolayers interactions, nanoparticles self assemble into a superlattice structure upon drying from a colloidal suspension on to the preformed lipid monolayers. This self-assembly mechanism produces monolayers with long-range ordering. However, rapid dewetting and high rate of evaporation can significantly undermine the extent of ordering. Using gold nanoparticles as vehicles for experimentation and by changing the monolayers and solvent, we here demonstrate that the extent of ordering of nanoparticles can be controlled. (C) 2010 Elsevier B.V. All rights reserved.

【 授权许可】

Free