Surface modification through air annealing Cu2ZnSn(S,Se)4 absorbers

THIN SOLID FILMS

卷:633

Article; Proceedings Paper

Larsen, J. K.¹  Ren, Y.¹  Ross, N.^1,2  Sarhammar, E.¹  Li, S. -Y.¹  Platzer-Bjorkman, C.¹ 

[1] Uppsala Univ, Angstrom Solar Ctr, Solid State Elect, Box 534, S-75121 Uppsala, Sweden

[2] Univ Oslo, Ctr Mat Sci & Nanotechnol, Box 1126, N-0318 Oslo, Norway

关键词: CZTS;    Kesterite;    Thin film solar cells;    Surface modification;    Passivation;   

DOI  :  10.1016/j.tsf.2016.08.030

来源: Elsevier

【 摘 要 】

Recent studies demonstrate that air annealing can have a positive effect on the device performance of Cu2ZnSn(SxSe1-x)(4)[CZTSSe] solar cells. In this work air annealing of the selenium containing CZTSSe is compared to the pure sulfide CZTS. It is discovered that the selenium containing absorbers benefit from air annealing at higher temperatures than selenium free absorbers. The highest efficiency obtained utilizing the air annealing treatment on selenium containing absorbers is 9.7%. We find that the band gap is narrowed when air annealing, which is partially explained by increased Cu-Zn disorder. Furthermore Zn enrichment of the surface after etching is identified as a possible cause of enhanced device performance. It is additionally observed that elemental selenium present on the CZTSSe surface is reduced in the air annealing treatment. Selenium removal is another possible explanation for the enhanced performance caused by the air annealing treatment. (C) 2016 Elsevier B.V. All rights reserved.

【 授权许可】

Free