Stable cyclic performance of nickel oxide-carbon composite anode for lithium-ion batteries

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Article

Susantyoko, Rahmat Agung^1,2  Wang, Xinghui²  Fan, Yu²  Xiao, Qizhen²  Fitzgerald, Eugene^1,3  Pey, Kin Leong^1,4  Zhang, Qing^1,2 

[1] Singapore MIT Alliance, Adv Mat Micro & Nanosyst, Singapore 637460, Singapore

[2] Nanyang Technol Univ, Sch Elect & Elect Engn, Singapore 639798, Singapore

[3] MIT, Dept Mat Sci & Engn, Cambridge, MA 02139 USA

[4] Singapore Univ Technol & Design, Singapore 138682, Singapore

关键词: Anodes;    Carbon;    Composites;    Lithium-ion batteries;    Nickel oxides;   

DOI  :  10.1016/j.tsf.2014.01.087

来源: Elsevier

【 摘 要 】

Nickel oxide (NiO) directly grown on nickel foam is regarded as a promising lithium ion battery anode material which shows good cyclic and rate performances with a theoretical specific capacity of 718 mA h g(-1). In this study, we demonstrated a carbon-incorporated NiO anode (NiO-C) with a capacity per unit area of 2.11 mA h cm(-2) and 1.76 mA h cm(-2) at 0.2 C and 0.5 C rates, respectively, fabricated by thermal oxidation of carbon coated nickel foam. The specific capacity of our NiO-C composite samples at 0.5 C rate is found to be typically 389.16mA h g(-1), with a stable cyclic performance up tomore than 100 cycles. This remarkable performance is apparently superior to the control samples of pure NiO samples. The improved performance is contributed to carbon incorporation which serves as a fluent channel for electrons and a flexible network preventing NiO nanostructures from structural deformation during charge and discharge processes. The advantage of using our approach is the easy preparation of the NiO-C composite using a simple two-step process: chemical vapor deposition of ethanol and annealing in air. (C) 2014 Elsevier B. V. All rights reserved.

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