Feasibility of luminescent multilayer sol-gel thermal barrier coating manufacturing for future applications in through-thickness temperature gradient sensing

SURFACE & COATINGS TECHNOLOGY

卷:260

Article; Proceedings Paper

Copin, Etienne¹  Sentenac, Thierry¹  Le Maoult, Yannick¹  Bias, Fabien^1,2  Ansart, Florence²  Vidal, Vanessa¹  Lours, Philippe¹ 

[1] Univ Toulouse, Mines Albi Inst Clement Ader, F-81013 Albi 09, France

[2] Univ Toulouse, UPS INP CNRS, Inst Camot CIRIMAT, F-31062 Toulouse 09, France

关键词: Thermal barrier coating;    Sol-gel;    Luminescence;    Phosphor;    Sensor;   

DOI  :  10.1016/j.surfcoat.2014.08.077

来源: Elsevier

【 摘 要 】

This paper investigates the feasibility of manufacturing sol-gel multilayer thermal barrier coatings (TBC) functionalized with different lanthanide ions Ln(3+) having distinct photo-luminescence emission wavelengths (Ln = Sm, Eu, Dy, Er, Tm) for future applications in temperature gradient sensing. Ln(3+) doped 9.75 mol% yttria stabilized zirconia (YSZ) powders were produced to study the effect of activator concentration on luminescence intensity and host matrix crystal structure. Self-quenching was found to limit the maximum signal-to-noise ratio achievable with Sm3+, Dy3+, Er3+ and Tm3+ activators, which was not the case for Eu3+ in the 1-10 mol% range. The increase in activator was found to affect the crystal structure of YSZ. A solution was proposed that suppressed this effect while significantly increasing the luminescence intensity of all activators. Finally a TBC sensor prototype integrating Eu3+, Er3+ and Dy3+ doped layers distributed throughout the thickness was successfully deposited by a dip-coating sal-gel process and showed promising through-thickness luminescence sensing capabilities. (C) 2014 Elsevier B.V. All rights reserved.

【 授权许可】

Free