Sulphate concentration in cave dripwater and speleothems: long-term trends and overview of its significance as proxy for environmental processes and climate changes

QUATERNARY SCIENCE REVIEWS

卷:127

Article

Borsato, Andrea¹  Frisia, Silvia¹  Wynn, Peter M.²  Fairchild, Ian J.³  Miorandi, Renza⁴ 

[1] Univ Newcastle, Sch Environm & Life Sci, Callaghan, NSW 2308, Australia

[2] Univ Lancaster, Lancaster Environm Ctr, Lancaster LA1 4YQ, England

[3] Univ Birmingham, Sch Geog Earth & Environm Sci, Birmingham B15 2TT, Edgbaston, England

[4] Grp Grotte SAT Emilio Roner, I-38068 Rovereto, TN, Italy

关键词: Sulphur;    Speleothems;    Karst water;    Volcanic eruptions;    Anthropogenic sulphur peak;   

DOI  :  10.1016/j.quascirev.2015.05.016

来源: Elsevier

【 摘 要 】

Sulphate concentrations in speleothems identify major volcanic eruptions, provide useful information on soil and aquifer dynamics and, in similar fashion to the C-14 bomb peak, its Anthropocene peak can be used to date recent cave formations. However, the transmission of S from the atmosphere to cave dripwater and its incorporation in speleothems is subjected to biogeochemical cycling and accurate studies of each cave site are needed in order to assess how the S atmospheric signal is modified and eventually encoded in speleothems. This study investigates the role of biogeochemical cycling and aquifer hydrology by utilising published and new dripwater and speleothem data from Grotta di Ernesto (ER) in northern Italy. Here we provide the first long-term record of sulphate concentration in cave dripwater based on over 20 years of measurements. Fast drip site st-ER1 is characterised by a continuous decrease in SO4 concentration from a high of 7.5 +/- 0.8 mg/l in 1993-1994 to a low of 2.2 +/- 0.2 mg/l in 2013-2014, and replicates with a delay of similar to 15 years the decline in the atmospheric SO2 emissions. The S-series of slow flow ER78 site is further delayed by similar to 4.5 years in relation to the S retention in the aquifer matrix. The dripwater data are used to extend the previously published S record (1810-1998 AD) of stalagmite ER78 and reconstruct the anthropogenic S-peak: this displays a delay of similar to 20 years with respect to the atmospheric S emission peak due to biogeochemical cycling and aquifer storage. However, sulphur recycling above the cave did not operate with the same degree of efficiency through time, which resulted in a variable time delay between S deposition and incorporation into the stalagmite. In the pre-Anthropocene era, and in particular during the cold Little Ice Age, biogeochemical cycling was far less efficient than today, and the fast transmission of the atmospheric signal allowed capture of S released during major volcanic eruptions by stalagmites. (C) 2015 Elsevier Ltd. All rights reserved.

【 授权许可】

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