An easy one-step procedure for the synthesis of novel β-functionalised tellurides

TETRAHEDRON

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Article

Tanini, Damiano¹  Grechi, Anna^1,2  Dei, Silvia²  Teodori, Elisabetta²  Capperucci, Antonella¹ 

[1] Univ Firenze, Dipartimento Chim Ugo Schiff, Via Lastruccia 3-13, I-50019 Sesto Fiorentino, Italy

[2] Univ Florence, Sez Sci Farmaceut & Nutraceut, Area Farmaco & Salute Bambino, NEUROFARBA Dipartimento Neurosci, Via U Schiff 6, I-50019 Sesto Fiorentino, FI, Italy

关键词: Organotellurium;    Tellurides;    Epoxides;    Thiiranes;    Aziridinps;    Ring opening;   

DOI  :  10.1016/j.tet.2017.07.061

来源: Elsevier

【 摘 要 】

Novel beta-hydroxy-,beta-amino- and beta-mercapto- dialkyl- and phenyl-alkyl tellurides have been achieved through regioselective ring opening reactions of oxiranes, aziridines and thiiranes with different Te-nucleophiles, including tellurosilanes. Tellurium-125 NMR chemical shifts of selected compounds have been measured. (C) 2017 Elsevier Ltd. All rights reserved.

【 授权许可】

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