Formyloxyacetoxyphenylmethane and 1,1-diacylals as versatile O-formylating and O-acylating reagents for alcohols

TETRAHEDRON

卷:74

Article

Chapman, Robert S. L.¹  Francis, Molly¹  Lawrence, Ruth¹  Tibbetts, Joshua D.¹  Bull, Steven D.¹ 

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

关键词: Formylation;    Acylation;    Alcohols;    1,1-Diacylals;   

DOI  :  10.1016/j.tet.2018.09.014

来源: Elsevier

【 摘 要 】

Formyloxyacetoxyphenylmethane, symmetric 1,1-diacylals and mixed 1-pivaloxy-l-acyloxy-1-phenylmethanes have been used as moisture stable O-formylating and O-acylating reagents for primary and secondary alcohols, allylic alcohols and phenols under solvent/catalyst free conditions to afford their corresponding esters in good yield. (C) 2018 Elsevier Ltd. All rights reserved.

【 授权许可】

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