期刊论文详细信息
TETRAHEDRON 卷:67
Heterocycles via intramolecular platinum-catalyzed propargylic substitution
Article
De Brabander, Jef K.1 
[1] Univ Texas SW Med Ctr Dallas, Dept Biochem, Dallas, TX 75390 USA
关键词: Propargylic substitution;    Tetrahydropyrans;    Morpholines;    Dioxanes;    Sulfamates;    Platinum catalysis;   
DOI  :  10.1016/j.tet.2011.03.115
来源: Elsevier
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【 摘 要 】

We report a Pt(II)-catalyzed cyclization of nucleophile-tethered propargylic acetates yielding substituted heterocycles containing multiple heteroatoms including morpholines, dioxanes, and sulfamates with high cis-selectivity. (C) 2011 Elsevier Ltd. All rights reserved.

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