Transfer hydrogenation of olefins catalysed by nickel nanoparticles

TETRAHEDRON

卷:65

Article

Alonso, Francisco¹ 

[1] Univ Alicante, Fac Ciencias, Dept Quim Organ, E-03080 Alicante, Spain

关键词: Hydrogen transfer;    Reduction;    Olefins;    Nickel nanoparticles;   

DOI  :  10.1016/j.tet.2009.10.057

来源: Elsevier

【 摘 要 】

Nickel nanoparticles have been found to effectively catalyse the hydrogen-transfer reduction of a variety of non-functionalised and functionalised olefins using 2-propanol as the hydrogen donor. The heterogeneous process has been shown to be highly chemoselective for certain substrates, with all the corresponding alkanes being obtained in high yields. A synthesis of the natural dihydrostilbene brittonin A is also reported based on the use of nickel nanoparticles. (C) 2009 Elsevier Ltd. All rights reserved.

【 授权许可】

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