Self immolative dioxetane based chemiluminescent probe for H2O2 detection

SENSORS AND ACTUATORS B-CHEMICAL

卷:239

Article

Seven, Ozlem¹  Sozmen, Fazli²  Turan, Ilke Simsek¹ 

[1] Bilkent Univ, UNAM Natl Nanotechnol Res Ctr, TR-06800 Ankara, Turkey

[2] Cumhuriyet Univ, Dept Nanotechnol Engn, TR-58140 Sivas, Turkey

关键词: Hydrogen peroxide;    Self-immolation;    1,2-dioxetanes;    Chemosensors;    Chemiluminescence;   

DOI  :  10.1016/j.snb.2016.09.120

来源: Elsevier

【 摘 要 】

Chemiluminescent detection of H2O2 has been achieved by using self immolative dioxetane based probe which enables the signal amplification via disassembly of two chemiluminogenic modules at the same time in response to single analyte. Upon treatment of the probe with H2O2, boronate ester was deprotected subsequently to trigger the decomposition of 1,2-dioxetane ring via CIEEL mechanism which results in light emission as a selective sign of H2O2. (C) 2016 Elsevier B.V. All rights reserved.

【 授权许可】

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