Deformation mechanism of high-density polyethylene probed by in situ Raman spectroscopy

POLYMER

卷:58

Article

Kida, Takumitsu¹  Oku, Tatsuya¹  Hiejima, Yusuke¹  Nitta, Koh-hei¹ 

[1] Kanazawa Univ, Dept Chem & Mat Sci, Kanazawa, Ishikawa 9201192, Japan

关键词: High-density polyethylene;    In situ Raman spectroscopy;    Mechanical properties;   

DOI  :  10.1016/j.polymer.2014.12.030

来源: Elsevier

【 摘 要 】

The microscopic mechanism of high-density polyethylene under uniaxial drawing is investigated using in situ Raman spectroscopy. From the peak shifts of the symmetric and anti-symmetric C-C stretching modes, it is found that the load sharing on the polymer chain in the yielding region is anisotropic with stretching along the chain and compression perpendicular to the chain. The orientation functions (< P2 > and < P4 >) as well as the orientation distribution function (N(theta)) are determined from the polarized Raman spectra. The molecular orientation with cold drawing is found to proceed more effectively for lower crystallinity specimens. In the yielding region, it is also found that N(theta) has a maximum at the polar angle theta = 30-70 degrees. This peculiar behavior in the microscopic scale is explained by the preferential collapse of spherulites and the existence of lamellar clusters as the bulky mobile units. (C) 2014 Elsevier Ltd. All rights reserved.

【 授权许可】

Free