Processing strategies for cellulose nanocrystal/polyethylene-co-vinyl alcohol composites

POLYMER

卷:126

Article

Orr, Matthew P.^1,2  Shofner, Meisha L.^1,2 

[1] Georgia Inst Technol, Sch Mat Sci & Engn, Atlanta, GA 30332 USA

[2] Georgia Inst Technol, Renewable Bioprod Inst, Atlanta, GA 30332 USA

关键词: Polymer nanocomposite;    Cellulose nanocrystals;    Composite processing;   

DOI  :  10.1016/j.polymer.2017.08.043

来源: Elsevier

【 摘 要 】

Cellulose nanocrystals (CNCs) have garnered significant attention due in part to the remarkable properties of crystalline cellulose displayed at the nanoscale coupled with its availability from renewable resources. However, challenges exist in dispersing CNCs in thermoplastic polymers and assessing CNC dispersion. The purpose of this research was to investigate the impact different processing protocols had on CNC dispersion in two polyethylene-co-vinyl alcohol (EVOH) matrices and the resulting microstructure of the nanocomposites. Three processing strategies were proposed: a melt processing technique, a solution casting technique, and a combination of solution casting followed by melt processing. Polarized optical microscopy images of the nanocomposites showed that improved CNC dispersion and changes to the nanocomposite microstructure were observed when the multi-step protocol was implemented. Additionally, changes in microstructure as a function of comonomer ratios of EVOH suggested CNC dispersion changed as a result of differences in polymer-particle compatibility. (C) 2017 Elsevier Ltd. All rights reserved.

【 授权许可】

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