Modification of poly(dimethylsiloxane) as a basis for surface wrinkle formation: Chemical and mechanical characterization

POLYMER

卷:98

Article

del Campo, Adolfo¹  Nogales, Aurora²  Ezquerra, Tiberio A.²  Rodriguez-Hernandez, Juan³ 

[1] Inst Ceram & Vidrio ICV CSIC, C Kelsen 5, Madrid 28049, Spain

[2] IEM CSIC, Inst Estruct Mat, Serrano 121, Madrid 28006, Spain

[3] Inst Ciencia & Tecnol Polimeros ICTP CSIC, C Juan de la Cierva 3, Madrid 28006, Spain

关键词: UVO;    Surface modification;    PDMS;    Surface mechanical properties;    Confocal Raman;    Surface degradation;    Depth profile;    Quantitative nanomechanical mapping;   

DOI  :  10.1016/j.polymer.2016.06.035

来源: Elsevier

【 摘 要 】

In this manuscript, the processes occurring during UV-ozone treatment on polydimethylsiloxane (PDMS) surfaces i.e. formation of a stiff silica-like layer and surface degradation have been studied. While the chemical changes have been evaluated using Confocal Raman Microscopy (CRM) with submicrometer resolution, partial surface degradation occurring during longer ozone treatments have been evidenced both by Optical Profilometry and AFM. Whereas previous studies reported the formation of a thin silica layer of around 20-30 nm up to 200 nm depending on the method employed, herein, we demonstrated that in effect a thin rigid layer is formed but instead of a sharp interface predicted by previous reports a gradient depth profile was obtained. CRM evidenced the formation of a 4 mu m layer of modified material. By Quantitative Nanomechanical Mapping (QNM) and based on the equations that predict the wrinkle formation, a surface layer thickness of around of 4.5 mu m was also determined. (C) 2016 Elsevier Ltd. All rights reserved.

【 授权许可】

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