Synthesis and gas permeation properties of a novel thermally-rearranged polybenzoxazole made from an intrinsically microporous hydroxyl-functionalized triptycene-based polyimide precursor

POLYMER

卷:121

Article

Alghunaimi, Fahd¹  Ghanem, Bader¹  Wang, Yingge¹  Salinas, Octavio¹  Alaslai, Nasser¹  Pinnau, Ingo¹ 

[1] King Abdullah Univ Sci & Technol, Adv Membranes & Porous Mat Ctr, Div Phys Sci & Engn, Program Chem & Biol Engn, Al Jazri Bldg 4, Thuwal 239556900, Saudi Arabia

关键词: Gas separations;    Polyimide;    Triptycene;    Thermal rearrangement;    Polybenzoxazole;   

DOI  :  10.1016/j.polymer.2017.06.006

来源: Elsevier

【 摘 要 】

A hydroxyl-functionalized triptycene-based polyimide of intrinsic microporosity (TDA1-APAF) was converted to a polybenzoxazole (PBO) by heat treatment at 460 degrees C under nitrogen atmosphere. TDA1APAF treated for 15 min (TR 460) resulted in a PBO conversion of 95% based on a theoretical weight loss of 11.7 wt% of the polyimide precursor. The BET surface area of the TR 460 (680 m(2) g(-1)) was significantly higher than that of the TDA1-APAF polyimide (260 m(2) g(-1)) as determined by nitrogen adsorption at 196 degrees C. Heating TDA1-APAF for 30 min (TRC 460) resulted in a weight loss of 13.5 wt%, indicating full conversion to PBO and partial main-chain degradation. The TR 460 membrane displayed excellent O-2 permeability of 311 Barrer coupled with an O-2/N-2 selectivity of 5.4 and CO2 permeability of 1328 Barrer with a CO2/CH4 selectivity of 27. Interestingly, physical aging over 150 days resulted in enhanced O-2/N-2 selectivity of 6.3 with an O-2 permeability of 185 Barrer. The novel triptycene-based TR 460 PBO outperformed all previously reported APAF-polyimide-based PBOs with gas permeation performance close to recently reported polymers located on the 2015 O-2/N-2 upper bound. Based on this study, thermally-rearranged membranes from hydroxyl-functionalized triptycene-based polyimides are promising candidate membrane materials for air separation, specifically in applications where space and weight of membrane systems are of utmost importance such as nitrogen production for inert atmospheres in fuel lines and tanks on aircrafts and off-shore oil-or natural gas platforms. Mixed-gas permeation experiments also demonstrated good performance of the TR 460 membrane for natural gas sweetening with a CO2 permeability of similar to 1000 Barrer and CO2/CH4 selectivity of 22 at a typical CO2 wellhead partial pressure of 10 bar. (C) 2017 Elsevier Ltd. All rights reserved.

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