Dynamics of monodisperse linear entangled polymer melts in extensional flow: The effect of excluded-volume interactions

POLYMER

卷:50

Article

Kabanemi, Kalonji K.¹  Hetu, Jean-Francois¹ 

[1] Natl Res Council Canada, IMI, Boucherville, PQ J4B 6Y4, Canada

关键词: Extensional flow;    Excluded-volume interactions;    Polymer melts;   

DOI  :  10.1016/j.polymer.2009.10.008

来源: Elsevier

【 摘 要 】

We present an extension of the Rouse-CCR tube model for linear entangled polymers, by incorporating interchain repulsive excluded-volume interactions, to interpret extensional viscosity data of narrow molecular weight distribution polystyrene melts in strong extensional flows. The expression for the stress tensor is also adapted to account for modifications of the effective tube diameter due to flow-induced chain stretch. Despite its simplicity, the resulting model correctly captures the extensional theological behavior of linear entangled monodisperse polystyrene melts already published in the literature. Crown Copyright (C) 2009 Published by Elsevier Ltd. All rights reserved.

【 授权许可】

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