Synthesis via direct (hetero)arylation polymerization, electrochemical and optical properties of poly (3,4-disubstituted)thiophenes

POLYMER

卷:182

Article

Grolleau, Jeremie¹  Legoupy, Stephanie¹  Frere, Pierre¹  Gohier, Frederic¹ 

[1] Univ Angers, MOLTECH Anjou, SFR MATRIX, CNRS,UMR 6200, 2 Bd Lavoisier, F-49045 Angers, France

关键词: Polythiophenes;    Direct heteroarylation polymerization;    Electronic properties;   

DOI  :  10.1016/j.polymer.2019.121811

来源: Elsevier

【 摘 要 】

Some poly (3,4-disubstituted)thiophenes bearing both cyano and alkoxy or thioalkoxy groups have been synthesized by direct (hetero)arylation polymerization (DHAP) of 2-iodo-3,4-disubstituted thiophenes. The electron donor and acceptor properties of substituents in positions 3 and 4 allow to adjust the HOMO and LUMO levels. On the other hand, in order to avoid the polymer solubility problems, long branched or unbranched alkyl chains have also been introduced. Thus polymers with alkoxy groups have led to complete absorption in the wavelength range of the visible spectrum whereas in the presence of thioalkoxy groups, the absorption of the visible spectrum is only partial. Theoretical calculations have shown that sulphur creates torsions leading to a non-planar polymer chain.

【 授权许可】

Free