Carbons derived from alcohol-treated bacterial cellulose with optimal porosity for Li-O2 batteries

RENEWABLE ENERGY

卷:177

Article

Wang, Wenhai¹  Khabazian, Siavash²  Roig-Sanchez, Soledad¹  Laromaine, Anna¹  Roig, Anna¹  Tonti, Dino¹ 

[1] ICMAB CSIC, Inst Ciencia Mat Barcelona, Campus UAB, Bellaterra 08193, Spain

[2] Tarbiat Modares Univ, Dept Mat Sci & Engn, Nanomat Grp, Tehran, Iran

关键词: Bacterial cellulose;    Solvent exchange;    Porous carbons;    Electrochemical surface area;    Li-O-2 batteries;   

DOI  :  10.1016/j.renene.2021.05.059

来源: Elsevier

【 摘 要 】

Porous carbons are important cathode materials for metal-air batteries, but the most usual methods to prepare these porous structures are complex and of high cost. We have prepared porous carbons from bacterial cellulose (BC) hydrogels by a simple water-alcohol solvent exchange before carbonization. Alcohol treatment facilitates looser and more open structures than untreated BC, resulting in porous carbon structures with high surface area, appropriate for electrochemical applications. Used as cathodes in lithium-oxygen batteries, the carbon derived from 1-butanol treated BC has excellent discharge capacity (5.6 mA h cm(-2)) and good cycle life. This work presents a sustainable, straightforward and fast way to prepare porous carbon materials from BC. (C) 2021 The Author(s). Published by Elsevier Ltd.

【 授权许可】

Free