Hydrochar derived from municipal sludge through hydrothermal processing: A critical review on its formation, characterization, and valorization

WATER RESEARCH

卷:199

Review

Liu, Huan¹  Basar, Ibrahim Alper¹  Nzihou, Ange²  Eskicioglu, Cigdem¹ 

[1] Univ British Columbia, UBC Bioreactor Technol Grp, Sch Engn, Okanagan Campus,1137 Alumni Ave, Kelowna, BC V1V 1V7, Canada

[2] Univ Toulouse, IMT Mines Albi, RAPSODEE, CNRS,UMR 5302, Campus Jarlard, F-81013 Albi 09, France

关键词: Municipal sludge;    Hydrochar;    Hydrothermal conversion;    Pathway;    Contaminants;    Waste valorization;   

DOI  :  10.1016/j.watres.2021.117186

来源: Elsevier

【 摘 要 】

Additional options for the sustainable treatment of municipal sludge are required due to the significant amounts of sludge, high levels of nutrients (e.g., C, N, and P), and trace constituents it contains. Hy-drothermal processing of municipal sludge has recently been recognized as a promising technology to ef-ficiently reduce waste volume, recover bioenergy, destroy organic contaminants, and eliminate pathogens. However, a considerable amount of solid residue, called hydrochar, could remain after hydrothermal treatment. This hydrochar can contain abundant amounts of energy (with a higher heating value up to 24 MJ/kg, dry basis), nutrients, and trace elements, as well as surface functional groups. The valorization of sludge-derived hydrochar can facilitate the development and application of hydrothermal technologies. This review summarizes the formation pathways from municipal sludge to hydrochar, specifically, the im-pact of hydrothermal conditions on reaction mechanisms and product distribution. Moreover, this study comprehensively encapsulates the described characteristics of hydrochar produced under a wide range of conditions: Yield, energy density, physicochemical properties, elemental distribution, contaminants of concern, surface functionality, and morphology. More importantly, this review compares and evaluates the current state of applications of hydrochar: Energy production, agricultural application, adsorption, hetero-geneous catalysis, and nutrient recovery. Ultimately, along with the identified challenges and prospects of valorization approaches for sludge-derived hydrochar, conceptual designs of sustainable municipal sludge management are proposed.& nbsp; (c) 2021 Elsevier Ltd. All rights reserved.

【 授权许可】

Free