Long-term electrode behavior during treatment of arsenic contaminated groundwater by a pilot-scale iron electrocoagulation system

WATER RESEARCH

卷:175

Article

Bandaru, Siva R. S.¹  Roy, Abhisek²  Gadgil, Ashok J.¹  van Genuchten, Case M.^3,4 

[1] Univ Calif Berkeley, Dept Civil & Environm Engn, Berkeley, CA 94720 USA

[2] Jadavpur Univ, Dept Civil Engn, Kolkata, India

[3] Univ Utrecht, Fac Geosci, Dept Earth Sci Geochem, Utrecht, Netherlands

[4] Geol Survey Denmark & Greenland GEUS, Dept Geochem, Copenhagen, Denmark

关键词: Anodic dissolution;    Electrode surface layers;    Iron electrocoagulation;    Arsenic removal;    Sustainable water treatment;   

DOI  :  10.1016/j.watres.2020.115668

来源: Elsevier

【 摘 要 】

Iron electrocoagulation (Fe-EC) is an effective technology to remove arsenic (As) from groundwater used for drinking. A commonly noted limitation of Fe-EC is fouling or passivation of electrode surfaces via rust accumulation over long-term use. In this study, we examined the effect of removing electrode surface layers on the performance of a large-scale (10,000 L/d capacity) Fe-EC plant in West Bengal, India. We also characterized the layers formed on the electrodes in active use for over 2 years at this plant. The electrode surfaces developed three distinct horizontal sections of layers that consisted of different minerals: calcite, Fe(III) precipitates and magnetite near the top, magnetite in the middle, and Fe(III) precipitates and magnetite near the bottom. The interior of all surface layers adjacent to the Fe(0) metal was dominated by magnetite. We determined the impact of surface layer removal by mechanical abrasion on Fe-EC performance by measuring solution composition (As, Fe, P, Si, Mn, Ca, pH, DO) and electrochemical parameters (total cell voltage and electrode interface potentials) during electrolysis. After electrode cleaning, the Fe concentration in the bulk solution increased substantially from 15.2 to 41.5 mu g/L. This higher Fe concentration led to increased removal of a number of solutes. For As, the concentration reached below the 10 mu g/L WHO MCL more rapidly and with less total Fe consumed (i.e. less electrical energy) after cleaning (128.4 mu g/L As removed per kWh) compared to before cleaning (72.9 mu g/L As removed per kWh). Similarly, the removal of P and Si improved after cleaning by 0.3 mg/L/kWh and 1.1 mg/L/kWh, respectively. Our results show that mechanically removing the surface layers that accumulate on electrodes over extended periods of Fe-EC operation can restore Fe-EC system efficiency (concentration of solute removed/kWh delivered). Since Fe release into the bulk solution substantially increased upon electrode cleaning, our results also suggest that routine electrode maintenance can ensure robust and reliable Fe-EC performance over year-long timescales. (C) 2020 The Authors. Published by Elsevier Ltd.

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