Reductions of aryl bromides in water at room temperature

TETRAHEDRON LETTERS

卷:56

Article

Fennewald, James C.¹  Landstrom, Evan B.¹  Lipshutz, Bruce H.¹ 

[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

关键词: Micellar catalysis;    Green chemistry;    Recycling;    Mild debromination;    Functional group tolerance;   

DOI  :  10.1016/j.tetlet.2015.02.066

来源: Elsevier

【 摘 要 】

Micellar nanoreactors derived from commercially available 'Nok' (SPGS-550-M), in the presence of Fu's catalyst and a mild hydride source (NaBH4), are useful for facile debromination of functionalized aromatic derivatives. This mild and environmentally responsible process is utilized in water at room temperature, and the reaction mixtures can be smoothly recycled. (C) 2015 Elsevier Ltd. All rights reserved.

【 授权许可】

Free