An efficient and cost-effective preparation of di-O-acetyl-D-rhamnal

TETRAHEDRON LETTERS

卷:54

Article

Miller, Justin N.¹  Pongdee, Rongson¹ 

[1] Sewanee Univ South, Dept Chem, Sewanee, TN 37383 USA

关键词: Carbohydrates;    Deoxysugars;    Glycosides;    Natural products;   

DOI  :  10.1016/j.tetlet.2013.04.035

来源: Elsevier

【 摘 要 】

We have developed a synthetic route to the frequently utilized deoxysugar building block di-O-acetyl-D-rhamnal originating from the inexpensive starting material methyl alpha-D-glucopyranoside. Our approach proceeds in five steps with minimal column chromatography purification needed to afford the title compound in good overall yield. (C) 2013 Elsevier Ltd. All rights reserved.

【 授权许可】

Free