Insulated π-conjugated metallopolymers

TETRAHEDRON LETTERS

卷:55

Article

Masai, Hiroshi¹  Terao, Jun¹  Tsuji, Yasushi¹ 

[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Nishikyo Ku, Kyoto 6158510, Japan

关键词: Insulated pi-conjugated polymer;    Metallopolymer;    Dendrimer;    Rotaxane;   

DOI  :  10.1016/j.tetlet.2014.05.078

来源: Elsevier

【 摘 要 】

Recently, there has been a progressive development of insulated pi-conjugated metallopolymers with accumulated features of pi-conjugated bridging units, transition metal complexes, and encapsulating moieties, as higher-order functionalized materials. A number of insulated conjugated metallopolymers have been successfully synthesized and their fascinating properties have been reported. In addition to the conventional features derived from pi-conjugation and transition metals, their insulated structures can compensate for solubility, a disadvantage in conventional metallopolymers, and enhance their functionalities, such as sensing, luminescence, and conduction. In this review, we summarize the synthetic methodologies, structural characteristics, and functionalities of one-dimensional insulated pi-conjugated metallopolymers, while focusing on the effect of transition metals and insulation on their properties. (C) 2014 Published by Elsevier Ltd.

【 授权许可】

Free