Rhodium(II) catalyzed cyclopropanation/cycloaddition reactions of the bis(diazo)piperidin-2-one system

TETRAHEDRON LETTERS

卷:56

Article

Bonderoff, Sara A.¹  Padwa, Albert¹ 

[1] Emory Univ, Dept Chem, Atlanta, GA 30322 USA

关键词: Rhodium(II);    Catalysis;    Carbenoid;    Cyclopropanation;    Dipolar cycloaddition;    Bis(diazo)indolin-2-one;   

DOI  :  10.1016/j.tetlet.2014.12.020

来源: Elsevier

【 摘 要 】

Bis(diazo)piperidin-2-ones that are devoid of a donor substituent in the 4-position undergo a one-pot cyclopropanation/cascade dipole formation/cycloaddition reaction to produce novel azapolycycles. (C) 2014 Elsevier Ltd. All rights reserved.

【 授权许可】

Free