Scandium triflate catalyzed ester synthesis using primary amides

TETRAHEDRON LETTERS

卷:55

Article

Atkinson, Benjamin N.¹  Williams, Jonathan M. J.¹ 

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

关键词: Amides;    Alcohols;    Scandium;    Esters;    Alcoholysis;   

DOI  :  10.1016/j.tetlet.2014.10.124

来源: Elsevier

【 摘 要 】

A scandium triflate (ScOTf)(3) catalyzed methodology has been developed to synthesize esters from primary amides. Various primary and secondary aliphatic alcohols have been shown to react in n-heptane with a range of primary amides for 24 h. (C) 2014 The Authors. Published by Elsevier Ltd.

【 授权许可】

Free