Transition metal-catalyzed reactions of N-sulfinyl imines

TETRAHEDRON LETTERS

卷:73

Article

Foubelo, Francisco^1,2,3  Najera, Carmen³  Sansano, Jose M.^1,2,3  Yus, Miguel³ 

[1] Univ Alicante, Dept Quim Organ, Apdo 99, Alicante 03080, Spain

[2] Univ Alicante, Inst Sintesis Organ ISO, Apdo 99, Alicante 03080, Spain

[3] Univ Alicante, Ctr Innovac Quim Avanzada ORFEO CINQA, Apdo 99, Alicante 03080, Spain

关键词: Chiral sulfinyl imines;    Transition metals;    Addition reactions;    Hydrogenations;    Transfer hydrogenations;   

DOI  :  10.1016/j.tetlet.2021.153104

来源: Elsevier

【 摘 要 】

Transition metal-catalyzed reactions of N-sulfinyl imines with several substrates lead to the corresponding chiral amines with high yields and diastereo- or enantioselectivities. As metals, titanium, copper, ruthenium, rhodium, palladium and silver have been successfully used as catalysts in different carbon-carbon forming reactions as well as hydrogenations with molecular hydrogen or transfer hydrogenations with isopropanol as hydrogen source. (C) 2021 Elsevier Ltd. All rights reserved.

【 授权许可】

Free