Mild and efficient synthesis of iodylarenes using Oxone as oxidant

TETRAHEDRON LETTERS

卷:57

Article

Soldatova, Natalia¹  Postnikov, Pavel¹  Troyan, Anna A.¹  Yoshimura, Akira²  Yusubov, Mekhman S.¹  Zhdankin, Viktor V.^1,2 

[1] Tomsk Polytech Univ, Tomsk 634050, Russia

[2] Univ Minnesota, Dept Chem & Biochem, Duluth, MN 55812 USA

关键词: Iodine;    Oxidation;    Iodylarenes;    Oxone;    Hypervalent iodine;   

DOI  :  10.1016/j.tetlet.2016.08.038

来源: Elsevier

【 摘 要 】

Mild and efficient method for the preparation of iodylarenes by oxidation of iodoarenes with Oxone in aqueous acetonitrile at room temperature is described. This new procedure allows the preparation of various iodylarenes with electron-donating or electron-withdrawing substituents in the aromatic ring including the previously unknown 1,2-diiodylbenzene. (C) 2016 Elsevier Ltd. All rights reserved.

【 授权许可】

Free